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Synthese (Subject) / Umwandlung Funktionellergruppen (Lesson)

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• Methyl/Alk/Aldehyd -> ArCOOH CrO3/K2CrO7/KMnO4
• Ar-Methyl/Alk/Aldehyd -> ArCOOH CrO3/K2CrO7/KMnO4
• R-CH2OH -> RCOOH CrO3/K2Cr2O7/KMnO4
• R-CHO -> RCOOH CrO3/K2Cr2O7/KMnO4
• sek. Alkohol -> Keton CrO3/K2Cr2O7/KMnO4
• R-CH2OH -> RCHO Pyridiniumdichromat
• sek. Alk. -> R-CH2-R 1. Tosylchlorid bildet Ester 2. LiAlH4 spaltet ihn
• R-CHO -> R-OH LiAlH4
• Keton -> sek. Alk LiAlH4
• Keton -> R-CH2-R C2H4(SH)2 + Raney Ni
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• Ester/Sre -> Alk x2 LiAlH4
• sek. Amid -> tert. Amin LiAlH4
• R-CN -> CH2-NH2 LiAlH4
• Ester -> Aldehyd Diisobutylaluminiumhydrid
• Carbonsrechlorid -> Aldehyd Lithium-tert-butoxy-aluminiumhydrid
• R-CH=CH-R -> R-C=_C-R 1. Br2 2. KOH
• Olefin -> Epoxid H2O2
• Olefin -> 2wert Alk (Cis) KMnO4
• Olefin -> 2wert Alk (trans) H2O2
• Dreif.b. -> trans Olefin? Li
• dreif.Bind. -> cis Olefin Lindlar
• Ar-NO2-> ArNH2 Sn/HCl
• Ar-NH2 -> ArNO2 CF3COOOH 

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